New routes to the preparation of [ru3(co)12], [h4ru4(co)12], [rucl2(pph3)3] and [rucl2(cod)]n from anglo platinum refinery

Chiririwa, Haleden (2013) New routes to the preparation of [ru3(co)12], [h4ru4(co)12], [rucl2(pph3)3] and [rucl2(cod)]n from anglo platinum refinery.

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Official URL: http://ir.nust.ac.zw/xmlui/handle/123456789/406

Abstract

Journal Article,New and improved routes for the preparation of ruthenium complexes are described. [Ru3(CO)12], [H4Ru4(CO)12], [RuCl2(PPh3)3] and [RuCl2(COD)]n have been prepared from [(NH4)2RuCl6] and [H2RuCl6]. Traditionally these ruthenium complexes have been prepared from commercially available RuCl3.3H2O, but here we describe their preparation from refinery materials.,National Research Foundation, DST-NRF Centre of Excellence in Catalysis and Anglo Platinum Corporation for funding this project.

Item Type: Article
Uncontrolled Keywords: Ruthenium complexes,Ruthenium trichloride trihydrate,Refinery materials,Ammonium hexachlororuthenate,Dihydrogen hexachlororuthenate
Divisions: Universities > State Universities > National University of Science and Technology
Depositing User: Mr. Edmore Sibanda
Date Deposited: 30 Nov 2015 22:01
Last Modified: 30 Nov 2015 22:01
URI: http://researchdatabase.ac.zw/id/eprint/1080

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